#--------------------------------------------------------------------------- # # This is a kinetic model (with accompanying thermochemistry and transport) in CHEMKIN format # that accompanies the following paper: # # Q. Meng, L. Lei, J. Lee, M.P. Burke. "On the role of HNNO in NOx formation." # Proceedings of the Combustion Institute (2023) in press, doi:10.1016/j.proci.2022.08.044. # # This model is essentially the model from Glarborg et al. (PECS 2018, 67:31-68) with the HNNO sub-model # from Meng et al. (2023) appended. # # NOTE: THIS CHEMKIN FILE WAS AUTOMATICALLY GENERATED BY CONVERTING A CANTERA FILE # REFER TO ORIGINAL CANTERA FILE FOR COMMENTS WITH REFERENCE INFORMATION # # Please address correspondence to: # # Michael P. Burke, Columbia University # mpburke@columbia.edu # # and consult the following website for any updates: # # https://burke.me.columbia.edu/ # #--------------------------------------------------------------------------- ELEMENTS O H N Ar He END SPECIES H2 O2 O3 H O OH HO2 H2O H2O2 NO NH3 NH2 NH N NNH N2H4 N2H3 N2H2 H2NN NH2OH H2NO HNOH HNO HON NO2 HONO HNO2 NO3 HONO2 N2O AR HE N2 t-ONNH c-ONNH ONHN H2NNO2 t-HNN(O)OH c-HNN(O)OH END REACTIONS H+O2<=>O+OH 1.000000E+14 0.0 15286.0 H2+O<=>H+OH 3.800000E+12 0.0 7948.0 DUPLICATE H2+O<=>H+OH 8.800000E+14 0.0 19175.0 DUPLICATE H2+OH<=>H+H2O 2.200000E+08 1.51 3430.0 2OH<=>H2O+O 2.000000E+07 1.651 631.0 DUPLICATE 2OH<=>H2O+O 2.600000E+11 -0.057 -827.0 DUPLICATE H2+M<=>2H+M 4.600000E+19 -1.4 104380.0 AR/0.0/H2/2.5/H2O/12.0/ AR+H2<=>AR+2H 5.800000E+18 -1.1 104380.0 H+O+M<=>OH+M 4.700000E+18 -1.0 0.0 AR/0.75/H2/2.5/H2O/12.0/ 2O+M<=>O2+M 1.900000E+13 0.0 -1788.0 AR/0.0/H2/2.5/H2O/12.0/ H2O+M<=>H+OH+M 6.100000E+27 -3.322 120790.0 H2/3.0/H2O/0.0/N2/2.0/O2/1.5/ 2H2O<=>H+H2O+OH 1.000000E+26 -2.44 120180.0 H+O2(+M)<=>HO2(+M) 4.700000E+12 0.44 0.0 LOW/ 6.366000E+20 -1.72 524.8 TROE/ 5.0000E-01 1.0000E-30 1.0000E+30 0.0000E+00/ AR/0.67/H2/2.0/H2O/14.0/O2/0.78/ H+HO2<=>H2+O2 2.800000E+06 2.09 -1451.0 H+HO2<=>2OH 7.100000E+13 0.0 295.0 H+HO2<=>H2O+O 1.400000E+12 0.0 0.0 HO2+O<=>O2+OH 2.900000E+10 1.0 -724.0 HO2+OH<=>H2O+O2 1.900000E+20 -2.49 584.0 DUPLICATE HO2+OH<=>H2O+O2 1.200000E+09 1.24 -1310.0 DUPLICATE 2HO2<=>H2O2+O2 1.200000E+09 0.7712 -1825.0 DUPLICATE 2HO2<=>H2O2+O2 1.300000E+12 0.295 7397.0 DUPLICATE H2O2(+M)<=>2OH(+M) 2.000000E+12 0.9 48749.0 LOW/ 2.500000E+24 -2.3 48749.0 TROE/ 4.3000E-01 1.0000E-30 1.0000E+30 0.0000E+00/ AR/1.0/H2/3.7/H2O/7.5/H2O2/7.7/N2/1.5/O2/1.2/ H+H2O2<=>H2O+OH 2.400000E+13 0.0 3970.0 H+H2O2<=>H2+HO2 4.800000E+13 0.0 7950.0 H2O2+O<=>HO2+OH 9.600000E+06 2.0 3970.0 H2O2+OH<=>H2O+HO2 1.700000E+12 0.0 318.0 DUPLICATE H2O2+OH<=>H2O+HO2 7.600000E+13 0.0 7270.0 DUPLICATE H+NH2(+M)<=>NH3(+M) 1.600000E+14 0.0 0.0 LOW/ 3.600000E+22 -1.76 0.0 TROE/ 5.0000E-01 1.0000E-30 1.0000E+30 1.0000E+30/ H+NH3<=>H2+NH2 6.400000E+05 2.39 10171.0 NH3+O<=>NH2+OH 9.400000E+06 1.94 6460.0 NH3+OH<=>H2O+NH2 2.000000E+06 2.04 566.0 HO2+NH3<=>H2O2+NH2 3.000000E+11 0.0 22000.0 H2+NH<=>H+NH2 2.100000E+13 0.0 15417.0 NH2+O<=>H+HNO 6.600000E+14 -0.5 0.0 NH2+O<=>NH+OH 7.000000E+12 0.0 0.0 DUPLICATE NH2+O<=>NH+OH 8.600000E-01 4.01 1673.0 DUPLICATE NH2+OH<=>H2O+NH 3.300000E+06 1.949 -217.0 HO2+NH2<=>NH3+O2 1.700000E+04 1.55 2027.0 HO2+NH2<=>H2NO+OH 2.500000E+17 -1.28 1166.0 HO2+NH2<=>H2O+HNO 1.600000E+07 0.55 525.0 DUPLICATE HO2+NH2<=>H2O+HNO 5.700000E+15 -1.12 707.0 DUPLICATE HO2+NH2<=>H2O+HON 2.100000E+07 0.64 811.0 NH2+O2<=>H2NO+O 2.600000E+11 0.4872 29050.0 NH2+O2<=>HNO+OH 2.900000E-02 3.764 18185.0 2NH2<=>NH+NH3 5.600000E+00 3.53 552.0 NH+NH2<=>N+NH3 9.600000E+03 2.46 107.0 N+NH2<=>2H+N2 7.000000E+13 0.0 0.0 HNO+NH2<=>NH3+NO 5.900000E+02 2.95 -3469.0 NH2+NO<=>H2O+N2 2.600000E+19 -2.369 870.0 NH2+NO<=>NNH+OH 4.300000E+10 0.294 -866.0 HONO+NH2<=>NH3+NO2 7.100000E+01 3.02 -4940.0 NH2+NO2<=>H2NO+NO 8.600000E+11 0.11 -1186.0 H+NH<=>H2+N 3.000000E+13 0.0 0.0 NH+O<=>H+NO 9.200000E+13 0.0 0.0 NH+OH<=>H+HNO 3.200000E+14 -0.376 -46.0 NH+OH<=>H2O+N 1.600000E+07 1.733 -576.0 NH+O2<=>HNO+O 2.400000E+13 0.0 13850.0 NH+O2<=>NO+OH 9.900000E+10 0.0 1530.0 2NH<=>N+NH2 5.700000E-01 3.88 342.0 N+NH<=>H+N2 3.000000E+13 0.0 0.0 HONO+NH<=>NH2+NO2 1.000000E+13 0.0 0.0 NH+NO2<=>N2O+OH 4.100000E+12 0.0 0.0 NH+NO2<=>HNO+NO 5.900000E+12 0.0 0.0 N+OH<=>H+NO 3.800000E+13 0.0 0.0 N+O2<=>NO+O 5.900000E+09 1.0 6280.0 N+NO<=>N2+O 9.400000E+12 0.14 0.0 NNH<=>H+N2 1.000000E+09 0.0 0.0 H+NNH<=>H2+N2 1.000000E+14 0.0 0.0 NNH+OH<=>H2O+N2 5.000000E+13 0.0 0.0 NNH+O2<=>HO2+N2 5.600000E+14 -0.385 -13.0 NH+NNH<=>N2+NH2 5.000000E+13 0.0 0.0 NH2+NNH<=>N2+NH3 5.000000E+13 0.0 0.0 NNH+NO<=>HNO+N2 5.000000E+13 0.0 0.0 NH2OH(+M)<=>NH2+OH(+M) 1.400000E+20 -1.31 64080.0 LOW/ 5.400000E+37 -5.96 66783.0 TROE/ 3.1000E-01 1.0000E-30 1.0000E+30 1.0000E+30/ H+NH2OH<=>H2+HNOH 4.800000E+08 1.5 6249.0 H+NH2OH<=>H2+H2NO 2.400000E+08 1.5 5067.0 NH2OH+O<=>HNOH+OH 3.300000E+08 1.5 3865.0 NH2OH+O<=>H2NO+OH 1.700000E+08 1.5 3010.0 NH2OH+OH<=>H2O+HNOH 1.500000E+04 2.61 -3537.0 NH2OH+OH<=>H2NO+H2O 1.500000E+05 2.28 -1296.0 NH2+NH2OH<=>HNOH+NH3 1.100000E-01 4.0 -97.0 NH2+NH2OH<=>H2NO+NH3 9.500000E+00 3.42 -1013.0 NH+NH2OH<=>HNOH+NH2 2.900000E-03 4.4 1564.0 NH+NH2OH<=>H2NO+NH2 1.500000E-03 4.6 2424.0 HO2+NH2OH<=>H2O2+HNOH 2.900000E+04 2.69 9557.0 HO2+NH2OH<=>H2NO+H2O2 1.400000E+04 2.69 6418.0 H2NO+M<=>H+HNO+M 2.800000E+24 -2.83 64915.0 H2O/10.0/ H2NO+M<=>HNOH+M 1.100000E+29 -4.0 44000.0 H2O/10.0/ H+H2NO<=>H2+HNO 3.000000E+07 2.0 2000.0 H+H2NO<=>NH2+OH 5.000000E+13 0.0 0.0 H2NO+O<=>HNO+OH 3.000000E+07 2.0 2000.0 H2NO+OH<=>H2O+HNO 1.000000E+14 0.0 0.0 H2NO+HO2<=>H2O2+HNO 2.900000E+04 2.69 -1600.0 H2NO+O2<=>HNO+HO2 2.300000E+02 2.994 16500.0 H2NO+NH2<=>HNO+NH3 3.000000E+12 0.0 1000.0 H2NO+NO<=>2HNO 2.000000E+04 2.0 13000.0 H2NO+NO2<=>HNO+HONO 4.400000E+04 2.64 4040.0 HNOH+M<=>H+HNO+M 2.000000E+24 -2.84 58934.0 H2O/10.0/ H+HNOH<=>NH2+OH 4.000000E+13 0.0 0.0 H+HNOH<=>H2+HNO 4.800000E+08 1.5 378.0 HNOH+O<=>HNO+OH 7.000000E+13 0.0 0.0 DUPLICATE HNOH+O<=>HNO+OH 3.300000E+08 1.5 -358.0 DUPLICATE HNOH+OH<=>H2O+HNO 2.400000E+06 2.0 -1192.0 HNOH+HO2<=>H2O2+HNO 2.900000E+04 2.69 -1600.0 HNOH+HO2<=>NH2OH+O2 2.900000E+04 2.69 -1600.0 HNOH+O2<=>HNO+HO2 3.000000E+12 0.0 25000.0 HNOH+NH2<=>HNO+NH3 1.800000E+06 1.94 -1152.0 HNOH+NO2<=>HNO+HONO 6.000000E+11 0.0 2000.0 H+NO(+M)<=>HNO(+M) 1.500000E+15 -0.41 0.0 LOW/ 2.400000E+14 0.206 -1550.0 TROE/ 8.2000E-01 1.0000E-30 1.0000E+30 1.0000E+30/ N2/1.6/ H+HNO<=>H2+NO 6.600000E+10 0.94 495.0 HNO+O<=>NO+OH 2.300000E+13 0.0 0.0 HNO+OH<=>H2O+NO 1.200000E+09 1.189 334.0 HNO+HO2<=>HNO2+OH 2.000000E+03 2.36 8980.0 HNO+O2<=>HO2+NO 2.000000E+13 0.0 16000.0 2HNO<=>H2O+N2O 9.000000E+08 0.0 3100.0 HNO+NO2<=>HONO+NO 4.400000E+04 2.64 4040.0 HO2+NO<=>NO2+OH 2.100000E+12 0.0 -497.0 NO+O(+M)<=>NO2(+M) 1.300000E+15 -0.75 0.0 LOW/ 4.720000E+24 -2.87 1550.0 TROE/ 7.5000E-01 1.0000E+03 1.0000E+05 1.0000E+30/ H+NO2<=>NO+OH 1.300000E+14 0.0 362.0 NO2+O<=>NO+O2 1.100000E+14 -0.52 0.0 HO2+NO2<=>HONO+O2 1.900000E+00 3.32 3044.0 HO2+NO2<=>HNO2+O2 1.900000E+01 3.26 4983.0 2NO2<=>2NO+O2 4.500000E+12 0.0 27599.0 2NO2<=>NO+NO3 9.600000E+09 0.73 20900.0 NO+OH(+M)<=>HONO(+M) 1.100000E+14 -0.3 0.0 LOW/ 3.392000E+23 -2.5 0.0 TROE/ 7.5000E-01 1.0000E-30 1.0000E+30 1.0000E+30/ H2+NO2<=>H+HONO 1.800000E+01 3.51 26300.0 DUPLICATE H2+NO2<=>H+HONO 2.400000E+01 3.62 35800.0 DUPLICATE H+HONO<=>HNO+OH 5.600000E+10 0.86 5000.0 H+HONO<=>H2O+NO 8.100000E+06 1.89 3850.0 HONO+O<=>NO2+OH 1.200000E+13 0.0 5960.0 HONO+OH<=>H2O+NO2 1.700000E+12 0.0 -520.0 HONO+NO2<=>HONO2+NO 2.000000E+11 0.0 32700.0 2HONO<=>H2O+NO+NO2 3.500000E-01 3.64 12140.0 HNO2(+M)<=>HONO(+M) 2.500000E+14 0.0 32300.0 LOW/ 3.100000E+18 0.0 31500.0 TROE/ 1.1490E+00 1.0000E-30 3.1250E+03 1.0000E+30/ H2+NO2<=>H+HNO2 2.400000E+02 3.15 31100.0 HNO2+O<=>NO2+OH 1.700000E+08 1.5 2000.0 HNO2+OH<=>H2O+NO2 4.000000E+13 0.0 0.0 NO2+O(+M)<=>NO3(+M) 3.500000E+12 0.24 0.0 LOW/ 2.500000E+20 -1.5 0.0 TROE/ 7.1000E-01 1.0000E-30 1.7000E+03 1.0000E+30/ H+NO3<=>NO2+OH 6.000000E+13 0.0 0.0 NO3+O<=>NO2+O2 1.000000E+13 0.0 0.0 NO3+OH<=>HO2+NO2 1.400000E+13 0.0 0.0 HO2+NO3<=>NO2+O2+OH 1.500000E+12 0.0 0.0 NO2+NO3<=>NO+NO2+O2 5.000000E+10 0.0 2940.0 NO2+OH(+M)<=>HONO2(+M) 3.000000E+13 0.0 0.0 LOW/ 2.938000E+25 -3.0 0.0 TROE/ 4.0000E-01 1.0000E-30 1.0000E+30 1.0000E+30/ H+HONO2<=>H2+NO3 5.600000E+08 1.5 16400.0 H+HONO2<=>H2O+NO2 6.100000E+01 3.3 6285.0 H+HONO2<=>HONO+OH 3.800000E+05 2.3 6976.0 HONO2+OH<=>H2O+NO3 1.000000E+10 0.0 -1240.0 N2O(+M)<=>N2+O(+M) 9.900000E+10 0.0 57901.0 LOW/ 6.000000E+14 0.0 57444.0 H2O/12.0/N2/1.7/O2/1.4/ N2O+O<=>2NO 9.200000E+13 0.0 27679.0 N2O+O<=>N2+O2 9.200000E+13 0.0 27679.0 N2O+OH<=>HO2+N2 1.300000E-02 4.72 36560.0 N2O+OH<=>HNO+NO 1.200000E-04 4.33 25080.0 N2O+NO<=>N2+NO2 5.300000E+05 2.23 46280.0 2NH2<=>H2+N2H2 1.700000E+08 1.62 11783.0 2NH2<=>H2+H2NN 7.200000E+04 1.88 8802.0 NH+NH2<=>H+N2H2 4.300000E+14 -0.272 -77.0 HNOH+NH2<=>N2H3+OH 1.000000E+01 3.46 -467.0 HNOH+NH2<=>H2NN+H2O 8.800000E+16 -1.08 1113.0 2NH2(+M)<=>N2H4(+M) 5.600000E+14 -0.414 66.0 LOW/ 1.600000E+34 -5.49 1987.0 TROE/ 3.1000E-01 1.0000E-30 1.0000E+30 1.0000E+30/ N2H4<=>H2+H2NN 1.400000E+14 0.0 74911.0 H+N2H4<=>H2+N2H3 7.000000E+12 0.0 2500.0 H+N2H4<=>NH2+NH3 2.300000E+05 1.42 8202.0 N2H4+O<=>N2H3+OH 1.500000E+11 0.0 -1270.0 N2H4+O<=>H2O+N2H2 2.900000E+11 0.0 -1270.0 N2H4+OH<=>H2O+N2H3 1.300000E+13 0.0 -318.0 N2H4+NH2<=>N2H3+NH3 7.600000E-01 4.0 4048.0 N2H4+NO<=>HNO+N2H3 6.000000E+01 3.16 30845.0 N2H4+NO2<=>HONO+N2H3 8.200000E+01 3.13 8860.0 N2H4+NO2<=>HNO2+N2H3 2.400000E-02 4.14 7946.0 H+N2H2<=>N2H3 1.300000E+14 0.0 3871.0 H+N2H3<=>H2+N2H2 2.400000E+08 1.5 -10.0 N2H3+O<=>N2H2+OH 1.700000E+08 1.5 -646.0 N2H3+O<=>HNO+NH2 3.000000E+13 0.0 0.0 N2H3+O=>H+NH2+NO 3.000000E+13 0.0 0.0 N2H3+OH<=>H2O+N2H2 1.200000E+06 2.0 -1192.0 N2H3+OH<=>H2NN+H2O 3.000000E+13 0.0 0.0 N2H3+OH<=>HNO+NH3 1.000000E+12 0.0 15000.0 HO2+N2H3<=>H2O2+N2H2 1.400000E+04 2.69 -1600.0 HO2+N2H3<=>N2H4+O2 9.200000E+05 1.94 2126.0 N2H3+NH2<=>N2H2+NH3 9.200000E+05 1.94 -1152.0 N2H3+NH2<=>H2NN+NH3 3.000000E+13 0.0 0.0 N2H3+NH<=>N2H2+NH2 2.000000E+13 0.0 0.0 N2H2+M<=>H+NNH+M 1.900000E+27 -3.05 66107.0 H2O/7.0/ H+N2H2<=>H2+NNH 1.100000E+14 0.0 3128.0 N2H2+O<=>NNH+OH 3.300000E+08 1.5 497.0 N2H2+O<=>NH2+NO 1.000000E+13 0.0 0.0 N2H2+OH<=>H2O+NNH 5.900000E+01 3.4 1360.0 N2H2+NH2<=>NH3+NNH 8.800000E-02 4.05 1610.0 N2H2+NH<=>NH2+NNH 2.400000E+06 2.0 -1192.0 N2H2+NO<=>N2O+NH2 4.000000E+12 0.0 11922.0 H2NN<=>H+NNH 3.400000E+26 -4.83 46228.0 H2NN<=>H2+N2 2.500000E+14 0.0 52785.0 H2NN<=>N2H2 1.300000E+14 0.0 46931.0 H+H2NN<=>H2+NNH 4.800000E+08 1.5 -894.0 H+H2NN<=>H+N2H2 7.000000E+13 0.0 0.0 H2NN+O<=>NNH+OH 3.300000E+08 1.5 -894.0 H2NN+O<=>NH2+NO 7.000000E+13 0.0 0.0 H2NN+OH<=>H2O+NNH 2.400000E+06 2.0 -1192.0 H2NN+OH=>H+NH2+NO 2.000000E+12 0.0 0.0 H2NN+HO2=>NH2+NO+OH 9.000000E+12 0.0 0.0 H2NN+HO2<=>H2O2+NNH 2.900000E+04 2.69 -1600.0 H2NN+O2<=>NH2+NO2 1.500000E+12 0.0 5961.0 H2NN+NH2<=>NH3+NNH 1.800000E+06 1.94 -1152.0 NH2+NO2<=>H2O+N2O 6.601E+17 -1.84 7313.4 PLOG / 9.999997E-04 1.269720E+18 -2.1 30.85 / PLOG / 9.999997E-03 1.269300E+18 -2.1 29.59 / PLOG / 9.999997E-02 1.327640E+18 -2.1 37.21 / PLOG / 9.999997E-01 2.860040E+18 -2.19 326.44 / PLOG / 9.999997E+00 2.689060E+19 -2.45 1590.7 / PLOG / 9.999997E+01 1.869450E+20 -2.62 4343.2 / PLOG / 9.999997E+02 6.601110E+17 -1.84 7313.4 / H+N2O<=>NH+NO 1.178800E+21 -1.61 37000.54 NH+NO<=>N2+OH 1.499130E+12 0.01 -488.09 H+N2O<=>NNH+O 1.853200E+19 -1.07 48152.33 NNH+O<=>N2+OH 6.625200E+12 0.05 -289.01 NNH+O<=>NH+NO 8.113630E+11 0.33 -328.22 H+N2O<=>N2+OH 9.355E+08 1.53 14915.0 PLOG / 9.999997E-04 1.824790E+03 3.09 10220.0 / PLOG / 9.999997E-03 5.970830E+03 2.95 10580.0 / PLOG / 9.999997E-02 2.324960E+04 2.79 10996.0 / PLOG / 9.999997E-01 1.341340E+05 2.57 11537.0 / PLOG / 9.999997E+00 1.861560E+06 2.26 12369.0 / PLOG / 9.999997E+01 7.984090E+07 1.81 13662.0 / PLOG / 9.999997E+02 9.355030E+08 1.53 14915.0 / H2NNO2<=>t-HNN(O)OH 1.787E+16 -1.3 34079.0 PLOG / 9.999997E-04 3.242330E+18 -3.52 28786.0 / PLOG / 9.999997E-03 1.007600E+20 -3.65 30532.0 / PLOG / 9.999997E-02 2.676820E+21 -3.76 32244.0 / PLOG / 9.999997E-01 2.496590E+22 -3.76 33753.0 / PLOG / 9.999997E+00 2.412960E+22 -3.51 34795.0 / PLOG / 9.999997E+01 2.219070E+20 -2.69 34892.0 / PLOG / 9.999997E+02 1.787290E+16 -1.3 34079.0 / H2NNO2<=>c-HNN(O)OH 8.608E+39 -7.88 56643.0 PLOG / 9.999997E-04 2.287570E+36 -9.13 66578.0 / PLOG / 9.999997E-03 3.496190E+35 -8.37 65002.0 / PLOG / 9.999997E-02 2.037100E+29 -6.14 58651.0 / PLOG / 9.999997E-01 6.452540E+30 -6.23 52575.0 / PLOG / 9.999997E+00 1.644590E+39 -8.22 53562.0 / PLOG / 9.999997E+01 1.978760E+42 -8.79 55587.0 / PLOG / 9.999997E+02 8.608280E+39 -7.88 56643.0 / H2NNO2<=>NH2+NO2 2.733E+36 -6.38 56495.0 PLOG / 9.999997E-04 4.209760E+44 -10.7 58550.0 / PLOG / 9.999997E-03 1.334600E+40 -9.02 56689.0 / PLOG / 9.999997E-02 1.514880E+38 -8.12 55242.0 / PLOG / 9.999997E-01 2.377840E+39 -8.13 55320.0 / PLOG / 9.999997E+00 1.640090E+40 -8.03 56160.0 / PLOG / 9.999997E+01 2.643720E+39 -7.5 56753.0 / PLOG / 9.999997E+02 2.733360E+36 -6.38 56495.0 / H2NNO2<=>H2O+N2O 8.963E+36 -6.91 58327.0 PLOG / 9.999997E-04 2.524440E+52 -13.0 59052.0 / PLOG / 9.999997E-03 3.303060E+44 -10.2 55899.0 / PLOG / 9.999997E-02 2.507220E+42 -9.29 54889.0 / PLOG / 9.999997E-01 2.491720E+42 -9.02 54947.0 / PLOG / 9.999997E+00 5.293000E+42 -8.9 55538.0 / PLOG / 9.999997E+01 6.596730E+41 -8.46 57105.0 / PLOG / 9.999997E+02 8.963420E+36 -6.91 58327.0 / t-HNN(O)OH<=>c-HNN(O)OH 1.194E+39 -7.51 45497.0 PLOG / 9.999997E-02 8.939730E+23 -5.07 46582.0 / PLOG / 9.999997E-01 1.906480E+28 -5.74 42884.0 / PLOG / 9.999997E+00 1.083020E+35 -7.13 43183.0 / PLOG / 9.999997E+01 9.922430E+38 -7.81 44574.0 / PLOG / 9.999997E+02 1.194450E+39 -7.51 45497.0 / t-HNN(O)OH<=>NH2+NO2 1.926E+32 -5.39 48150.0 PLOG / 9.999997E-04 3.211450E+20 -3.51 42071.0 / PLOG / 9.999997E-03 3.591320E+23 -4.18 42448.0 / PLOG / 9.999997E-02 2.674940E+27 -5.07 42954.0 / PLOG / 9.999997E-01 6.160690E+31 -6.04 44050.0 / PLOG / 9.999997E+00 6.677230E+34 -6.63 45595.0 / PLOG / 9.999997E+01 2.000790E+35 -6.5 47205.0 / PLOG / 9.999997E+02 1.925530E+32 -5.39 48150.0 / t-HNN(O)OH<=>H2O+N2O 4.036E+33 -5.87 46034.0 PLOG / 9.999997E-04 6.749610E+24 -4.71 41139.0 / PLOG / 9.999997E-03 7.815150E+27 -5.37 41637.0 / PLOG / 9.999997E-02 3.192330E+31 -6.19 42547.0 / PLOG / 9.999997E-01 1.741400E+34 -6.76 43473.0 / PLOG / 9.999997E+00 3.153190E+35 -6.89 44063.0 / PLOG / 9.999997E+01 1.678870E+36 -6.84 45112.0 / PLOG / 9.999997E+02 4.036430E+33 -5.87 46034.0 / c-HNN(O)OH<=>NH2+NO2 3.210E+34 -6.1 50687.0 PLOG / 9.999997E-04 1.081240E+04 0.45 44733.0 / PLOG / 9.999997E-03 2.658180E+16 -2.58 52345.0 / PLOG / 9.999997E-02 5.459150E+18 -2.95 47164.0 / PLOG / 9.999997E-01 3.535970E+25 -4.54 43719.0 / PLOG / 9.999997E+00 9.509020E+32 -6.25 45143.0 / PLOG / 9.999997E+01 1.326920E+36 -6.82 48109.0 / PLOG / 9.999997E+02 3.210230E+34 -6.1 50687.0 / c-HNN(O)OH<=>H2O+N2O 1.182E+14 -0.49 26625.0 PLOG / 9.999997E-04 1.147150E+16 -2.67 21110.0 / PLOG / 9.999997E-03 5.129620E+17 -2.84 22915.0 / PLOG / 9.999997E-02 1.120260E+19 -2.92 24613.0 / PLOG / 9.999997E-01 6.843930E+19 -2.86 26087.0 / PLOG / 9.999997E+00 4.648840E+19 -2.54 27090.0 / PLOG / 9.999997E+01 3.001580E+17 -1.68 27163.0 / PLOG / 9.999997E+02 1.181560E+14 -0.49 26625.0 / # ************************************************************************ # HNNO subset * # ************************************************************************ H+N2O(+M)<=>t-ONNH(+M) 1.700000E+04 3.05 6530.0 LOW/ 1.270000E+27 -3.48 7030.0 TROE/ 1.2000E-01 1.0000E-30 1.0000E+30 0.0000E+00/ H2/3.0/H2O/21.0/N2/1.5/O2/1.1/ H+N2O(+M)<=>c-ONNH(+M) 2.370000E-02 4.81 4790.0 LOW/ 1.230000E+25 -2.94 6770.0 TROE/ 1.0000E-01 1.0000E-30 1.0000E+30 0.0000E+00/ H2/3.0/H2O/21.0/N2/1.5/O2/1.1/ H+N2O(+M)<=>ONHN(+M) 5.910000E-17 9.29 11900.0 LOW/ 4.800000E+20 -1.93 14400.0 TROE/ 7.5000E-02 1.0000E-30 1.0000E+30 0.0000E+00/ H2/3.0/H2O/21.0/N2/1.5/O2/1.1/ t-ONNH(+M)<=>c-ONNH(+M) 1.340000E+04 3.36 23000.0 LOW/ 1.030000E+17 -0.801 16900.0 TROE/ 7.4000E-02 1.0000E-30 1.0000E+30 0.0000E+00/ H2/3.0/H2O/21.0/N2/1.5/O2/1.1/ t-ONNH<=>N2+OH 1.177E+18 -2.0 35804.0 PLOG / 9.999997E-04 5.491740E+20 -4.92 27957.0 / PLOG / 9.999997E-03 7.191390E+19 -4.47 28290.0 / PLOG / 9.999997E-02 1.366140E+17 -3.44 28122.0 / PLOG / 9.999997E-01 1.870150E+14 -2.27 28300.0 / PLOG / 9.999997E+00 1.167970E+14 -1.76 30057.0 / PLOG / 9.999997E+01 6.529300E+16 -2.06 33255.0 / PLOG / 9.999997E+02 1.176900E+18 -2.0 35804.0 / c-ONNH<=>N2+OH 8.813E+05 1.43 23724.0 PLOG / 9.999997E-04 2.723670E+07 -0.96 17410.0 / PLOG / 9.999997E-03 1.320380E+07 -0.71 17789.0 / PLOG / 9.999997E-02 2.650660E+05 -0.01 17748.0 / PLOG / 9.999997E-01 1.035200E+03 1.0 17830.0 / PLOG / 9.999997E+00 4.688300E+02 1.52 19263.0 / PLOG / 9.999997E+01 9.611670E+04 1.32 21935.0 / PLOG / 9.999997E+02 8.813370E+05 1.43 23724.0 / ONHN<=>N2+OH 4.278E+14 -0.89 21729.0 PLOG / 9.999997E-04 2.591180E+05 -0.51 10529.0 / PLOG / 9.999997E-03 1.157600E+06 -0.4 11592.0 / PLOG / 9.999997E-02 1.039550E+06 -0.06 12507.0 / PLOG / 9.999997E-01 6.616590E+05 0.36 13590.0 / PLOG / 9.999997E+00 2.642920E+07 0.33 15729.0 / PLOG / 9.999997E+01 3.662820E+11 -0.41 19036.0 / PLOG / 9.999997E+02 4.277540E+14 -0.89 21729.0 / OH+c-ONNH<=>H2NNO2 5.595E+29 -5.79 5235.4 PLOG / 9.999997E-04 6.552870E+07 -1.75 12568.0 / PLOG / 9.999997E-03 9.286440E+12 -2.89 16148.0 / PLOG / 9.999997E-02 1.740970E+18 -4.09 18328.0 / PLOG / 9.999997E-01 1.056300E+15 -2.98 8984.3 / PLOG / 9.999997E+00 6.555940E+19 -4.01 3294.9 / PLOG / 9.999997E+01 1.337880E+28 -5.85 3491.3 / PLOG / 9.999997E+02 5.594600E+29 -5.79 5235.4 / OH+c-ONNH<=>t-HNN(O)OH 1.234E+27 -5.0 3790.3 PLOG / 9.999997E-04 1.488250E+30 -7.88 36355.0 / PLOG / 9.999997E-03 1.555740E+31 -7.86 37492.0 / PLOG / 9.999997E-02 1.981560E+17 -3.91 20340.0 / PLOG / 9.999997E-01 9.554910E+09 -1.69 7400.0 / PLOG / 9.999997E+00 4.064670E+15 -2.94 2091.8 / PLOG / 9.999997E+01 1.689450E+24 -4.8 2306.7 / PLOG / 9.999997E+02 1.234060E+27 -5.0 3790.3 / OH+c-ONNH<=>c-HNN(O)OH 6.310E+27 -5.23 4345.7 PLOG / 9.999997E-01 1.361960E+06 -0.76 8237.6 / PLOG / 9.999997E+00 4.286570E+13 -2.42 1856.7 / PLOG / 9.999997E+01 2.784050E+24 -4.87 2368.7 / PLOG / 9.999997E+02 6.310240E+27 -5.23 4345.7 / OH+c-ONNH<=>NH2+NO2 2.896E+15 -0.98 2546.2 PLOG / 9.999997E-04 1.502660E+14 -0.65 626.3 / PLOG / 9.999997E-03 1.502640E+14 -0.65 626.3 / PLOG / 9.999997E-02 1.502700E+14 -0.65 626.3 / PLOG / 9.999997E-01 1.503170E+14 -0.65 626.3 / PLOG / 9.999997E+00 1.507780E+14 -0.65 626.38 / PLOG / 9.999997E+01 2.281760E+14 -0.7 784.21 / PLOG / 9.999997E+02 2.895600E+15 -0.98 2546.2 / OH+c-ONNH<=>OH+t-ONNH 1.841E+14 -0.65 3175.2 PLOG / 9.999997E-04 8.206850E+12 -0.3 1159.1 / PLOG / 9.999997E-03 8.207330E+12 -0.3 1159.2 / PLOG / 9.999997E-02 8.211670E+12 -0.3 1159.4 / PLOG / 9.999997E-01 8.255210E+12 -0.3 1162.1 / PLOG / 9.999997E+00 8.724700E+12 -0.31 1189.5 / PLOG / 9.999997E+01 1.677760E+13 -0.38 1501.8 / PLOG / 9.999997E+02 1.841170E+14 -0.65 3175.2 / OH+c-ONNH<=>H2O+N2O 6.756E+15 -1.18 2088.5 PLOG / 9.999997E-04 5.956530E+14 -0.91 668.48 / PLOG / 9.999997E-03 5.956490E+14 -0.91 668.48 / PLOG / 9.999997E-02 5.957010E+14 -0.91 668.46 / PLOG / 9.999997E-01 5.960470E+14 -0.91 668.23 / PLOG / 9.999997E+00 5.993370E+14 -0.91 665.78 / PLOG / 9.999997E+01 7.477930E+14 -0.94 710.78 / PLOG / 9.999997E+02 6.755520E+15 -1.18 2088.5 / OH+t-ONNH<=>H2NNO2 6.821E+29 -5.71 7282.1 PLOG / 9.999997E-04 2.983050E+24 -6.22 12272.0 / PLOG / 9.999997E-03 1.461610E+22 -5.3 10109.0 / PLOG / 9.999997E-02 1.395470E+21 -4.77 6968.1 / PLOG / 9.999997E-01 2.260470E+23 -5.11 3594.3 / PLOG / 9.999997E+00 8.183850E+28 -6.26 3437.1 / PLOG / 9.999997E+01 8.516210E+31 -6.68 5301.1 / PLOG / 9.999997E+02 6.820860E+29 -5.71 7282.1 / OH+t-ONNH<=>t-HNN(O)OH 2.570E+27 -4.97 5060.1 PLOG / 9.999997E-04 1.423340E+21 -5.39 12576.0 / PLOG / 9.999997E-03 1.345760E+20 -4.83 11019.0 / PLOG / 9.999997E-02 9.962430E+16 -3.74 5875.4 / PLOG / 9.999997E-01 3.007810E+19 -4.15 2538.7 / PLOG / 9.999997E+00 7.809810E+24 -5.25 2309.6 / PLOG / 9.999997E+01 1.263780E+28 -5.63 3640.5 / PLOG / 9.999997E+02 2.570250E+27 -4.97 5060.1 / OH+t-ONNH<=>c-HNN(O)OH 4.628E+27 -5.01 4131.8 PLOG / 9.999997E-04 3.687010E-56 15.1 -44419.0 / PLOG / 9.999997E-03 1.086200E+23 -5.5 34725.0 / PLOG / 9.999997E-02 6.926240E+15 -3.34 17962.0 / PLOG / 9.999997E-01 4.913300E+10 -1.69 2195.3 / PLOG / 9.999997E+00 9.493360E+21 -4.41 1741.9 / PLOG / 9.999997E+01 7.222410E+27 -5.53 3388.6 / PLOG / 9.999997E+02 4.628470E+27 -5.01 4131.8 / OH+t-ONNH<=>NH2+NO2 8.170E+18 -2.06 6655.5 PLOG / 9.999997E-04 2.247300E+16 -1.44 1233.9 / PLOG / 9.999997E-03 2.247430E+16 -1.44 1233.9 / PLOG / 9.999997E-02 2.249410E+16 -1.44 1234.3 / PLOG / 9.999997E-01 2.273460E+16 -1.44 1238.7 / PLOG / 9.999997E+00 3.516670E+16 -1.5 1408.2 / PLOG / 9.999997E+01 1.431590E+18 -1.92 3172.1 / PLOG / 9.999997E+02 8.170000E+18 -2.06 6655.5 / OH+t-ONNH<=>H2O+N2O 2.239E+14 -0.62 1738.5 PLOG / 9.999997E-04 9.168590E+13 -0.55 338.27 / PLOG / 9.999997E-03 9.168470E+13 -0.55 338.26 / PLOG / 9.999997E-02 9.166780E+13 -0.55 338.14 / PLOG / 9.999997E-01 9.144860E+13 -0.55 336.72 / PLOG / 9.999997E+00 9.302280E+13 -0.55 338.04 / PLOG / 9.999997E+01 2.206610E+14 -0.65 720.23 / PLOG / 9.999997E+02 2.239120E+14 -0.62 1738.5 / O2+t-ONNH<=>HO2+N2O 3.664330E-02 4.341195 11952.478477 O2+t-ONNH<=>HNO2+NO 2.868240E+03 2.443551 31043.200598 O2+t-ONNH<=>O2+c-ONNH 1.049740E+04 2.089796 37212.565075 O2+c-ONNH<=>HO2+N2O 9.874430E+00 3.498286 14772.297992 O2+c-ONNH<=>HNO2+NO 5.844930E+04 2.189037 31165.569646 O2+ONHN<=>HNO+NO2 3.000000E+13 0.0 0.0 O2+ONHN<=>HO2+N2O 3.000000E+13 0.0 0.0 H+t-ONNH<=>NH2+NO 4.000000E+13 0.0 0.0 H+t-ONNH<=>H+N2+OH 1.500000E+13 0.0 0.0 H+t-ONNH<=>H2O+N2 6.000000E+12 0.0 0.0 H+c-ONNH<=>H+t-ONNH 1.000000E+13 0.0 0.0 H+c-ONNH<=>NH2+NO 1.800000E+13 0.0 0.0 H+c-ONNH<=>H+N2+OH 6.000000E+11 0.0 0.0 H+c-ONNH<=>H2O+N2 9.000000E+11 0.0 0.0 H+ONHN<=>NH2+NO 6.000000E+13 0.0 0.0 H+ONHN<=>H+N2+OH 6.000000E+13 0.0 0.0 H+ONHN<=>H2O+N2 6.000000E+13 0.0 0.0 OH+t-ONNH<=>HNOH+NO 3.000000E+13 0.0 0.0 OH+c-ONNH<=>HNOH+NO 3.000000E+13 0.0 0.0 OH+ONHN<=>HNOH+NO 3.000000E+13 0.0 0.0 OH+t-ONNH<=>H2O+N2O 3.000000E+13 0.0 0.0 OH+c-ONNH<=>H2O+N2O 3.000000E+13 0.0 0.0 OH+ONHN<=>H2O+N2O 3.000000E+13 0.0 0.0 O+t-ONNH<=>HNO+NO 6.000000E+13 0.0 0.0 O+c-ONNH<=>HNO+NO 6.000000E+13 0.0 0.0 O+ONHN<=>HNO+NO 6.000000E+13 0.0 0.0 O+t-ONNH<=>N2O+OH 6.000000E+13 0.0 0.0 O+c-ONNH<=>N2O+OH 6.000000E+13 0.0 0.0 O+ONHN<=>N2O+OH 6.000000E+13 0.0 0.0 t-ONNH<=>ONHN 7.842E+03 1.0095 38211.9 PLOG / 9.999997E-01 3.750000E-15 3.6858 16505.6 / PLOG / 9.999997E+00 7.037298E-01 0.40308 30406.4 / PLOG / 9.999997E+01 7.635485E+00 0.90702 33467.6 / PLOG / 9.999997E+02 7.841800E+03 1.0095 38211.9 / c-ONNH<=>ONHN 9.237E+00 1.8016 31599.1 PLOG / 9.999997E-01 6.190000E-27 6.9749 2480.55 / PLOG / 9.999997E+00 3.930000E-06 1.9127 23095.3 / PLOG / 9.999997E+01 1.031151E-03 1.9869 26555.8 / PLOG / 9.999997E+02 9.237246E+00 1.8016 31599.1 / # ************************************************************************ # END HNNO subset * # ************************************************************************ END